Izvorni kod stranice Monociklični monoterpen keton monooksigenaza

{{Infobox Enzim
| Name = Monociklični monoterpen keton monooksigenaza
| EC_number = 1.14.13.105
| CAS_number = 
| IUBMB_EC_number = 1/14/13/105
| GO_code = 
| image = 
| width = 
| caption =
}}
'''Monociklični monoterpen keton monooksigenaza''' ({{EC broj|1.14.13.105}}, ''1-hidroksi-2-oksolimonen 1,2-monooksigenaza'', ''dihidrokarvonska 1,2-monooksigenaza'', ''MMKMO'') je [[enzim]] sa sistematskim imenom ''(-)-menton,NADPH:kiseonik oksidoreduktaza''.<ref>{{cite journal | title = ''Rhodococcus erythropolis'' DCL14 contains a novel degradation pathway for limonene | url = https://archive.org/details/sim_applied-and-environmental-microbiology_1999-05_65_5/page/2092 |author = van der Werf, M.J., Swarts, H.J. and de Bont, J.A. |journal = Appl. Environ. Microbiol. |date = 1999 |volume = 65 |pages = 2092-2102 |pmid = 10224006}}</ref><ref>{{cite journal | title = Purification and characterization of a Baeyer-Villiger mono-oxygenase from ''Rhodococcus erythropolis'' DCL14 involved in three different monocyclic  monoterpene degradation pathways | url = https://archive.org/details/sim_biochemical-journal_2000-05-01_347/page/n102 |author = Van Der Werf, M.J. |journal = Biochem. J. |date = 2000 |volume = 347 |pages = 693-701 |pmid = 10769172}}</ref><ref>{{cite journal | title = Metabolism of carveol and dihydrocarveol in ''Rhodococcus erythropolis'' DCL14 |author = van der Werf, M.J. and Boot, A.M. |journal = Microbiology |date = 2000 |volume = 146 |pages = 1129-1141 |pmid = 10832640}}</ref> Ovaj enzim [[Kataliza|katalizuje]] sledeću [[hemijska reakcija|hemijsku reakciju]]

: (1) (-)-menton + NADPH + H<sup>+</sup> + O<sub>2</sub> <math>\rightleftharpoons</math> (4R,7S)-7-izopropil-4-metiloksepan-2-on + NADP<sup>+</sup> + H<sub>2</sub>O
:(2) dihidrokarvon + NADPH + H<sup>+</sup> + O<sub>2</sub> <math>\rightleftharpoons</math> 4-izopropenil--7-metiloksepan-2-on + NADP<sup>+</sup> + H<sub>2</sub>O
:(3) (izo)-dihidrokarvon + NADPH + H<sup>+</sup> + O<sub>2</sub> <math>\rightleftharpoons</math> 6-izopropenil--3-metiloksepan-2-on + NADP<sup>+</sup> + H<sub>2</sub>O
:(4a) 1-hidroksimenth-8-en-2-on + NADPH + H<sup>+</sup> + O<sub>2</sub> <math>\rightleftharpoons</math> 7-hidroksi-4-izopropenil--7-metiloksepan-2-on + NADP<sup>+</sup> + H<sub>2</sub>O
:(4b) 7-hidroksi-4-izopropenil--7-metiloksepan-2-on <math>\rightleftharpoons</math> 3-izopropenil--6-oksoheptanoat (spontana reakcija)

Ovaj enzim je flavoprotein (FAD).

== Reference ==
{{reflist}}

== Literatura ==
{{refbegin|2}}
* {{PriceEnzymology3rd}}
* {{TooneAdvancesInEnzymology}}
* {{Branden ProteinStructure2nd}}
* {{SegelEnzymeKinetics}}
* {{CopelandEvaluationOfEnzymeInhibitors2nd}}
* {{MichalBiochemicalPathways}}
{{refend}}

== Vanjske veze ==
* {{MeshName|Monocyclic+monoterpene+ketone+monooxygenase}}

{{Enzimi}}

[[Kategorija:EC 1.14.13]]